Comparison of sampling efficiency and storage stability on different sorbents for determination of solvents in occupational air

Sammendrag

This study describes the sampling efficiency and storage stability of compounds typically present in occupational atmospheres on the sorbents Anasorb CSC, Anasorb 747, and Chromosorb 106. The selection of compounds included in the study contained aliphatic and aromatic hydrocarbons, alcohols, esters, glycol ethers, ketones, and halogenated compounds, thus representing a wide range of chemical and physical properties. The different sorbent tubes were simultaneously exposed to the selected compounds as three different mixtures of solvent vapours in air, and storage both at room temperature and at -22degreesC was investigated. The sorbent tubes were stored and analyzed at two different laboratories. The sampling efficiencies of all the investigated compounds were excellent on Anasorb CSC and Anasorb 747, while Chromosorb 106 did not give such good results for the most volatile compounds under study. The room temperature storage stability on Chromosorb 106, however, was good for all compounds, although formation of artefacts was observed during storage, a disadvantage that was substantially reduced by storage at -22degreesC. The room temperature storage stability on Anasorb CSC was good for all compounds except some of the ketones. The room temperature storage stability of these ketones, especially cyclohexanone and 2-butanone, was much better on Anasorb 747, which still showed the same excellent storage stability for the remaining compounds. When stored in a freezer, the storage stability of all compounds, including the ketones, was very good on all sorbents. Among the sorbents under study, Anasorb 747 appears to be the most suitable all-round sorbent for monitoring volatile compounds in occupational air, with satisfactory capabilities regarding both sampling efficiency and storage stability.